The pseudo molecular ion m/z 1175.6608 ([M+Na] + ) was unequivocally identified as sodium adduct (C 57 H 96 N 6 O 18 Na) of cereulide ( 1 ) and, together with the corresponding [M+K] + ( m/z 1191.6356) and [M+NH 4 ] + ion ( m/z 1170.7072), was confirmed by co-chromatography with a purified cereulide reference 17,18
Wooten SV, Wang F, Roth ME, Liu G, Livingston JA, Amini B, Gilchrist SC, Hildebrandt M , Kleinerman ES
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